Ratiometric fluorescence determination of hydrogen peroxide using carbon dot-embedded Ag@EuWO₄(OH) nanocomposites

A sheet-like carbon dot-embedded Ag@EuWO₄(OH) luminescent nanoprobe was successfully developed for assaying hydrogen peroxide. Firstly, the carbon dot-embedded EuWO₄(OH) nanosheets were prepared in a Eu(NO₃)₃·6H₂O-(NH₄)₁₀H₂(W₂O₇)₆·xH₂O-CS(NH₂)₂ hydrothermal synthetic system. Subsequently, the carbon dot-embedded EuWO₄(OH) was functionalized by Ag nanoparticles using an in situ photochemical deposition strategy upon ultraviolet light irradiation. Taking advantage of the dual emissions of the luminescence from carbon dots and characteristic red transitions of Eu³⁺ ions in the integrated system, the carbon dot-embedded Ag@EuWO₄(OH) luminescent composites exhibit ratiometric fluorescence responsive activity towards hydrogen peroxide. The luminescent intensity ratio of Eu³⁺ (614 nm) to carbon dots (389 nm) shows a polynomial function with changing hydrogen peroxide concentration. The corresponding detection limit is 60 μM at a signal-to-noise ratio of 3 (S/N = 3) implying the potential use of the carbon dot-embedded Ag@EuWO₄(OH) as nanoprobe. The method was applied to the quantification of H₂O₂ in real samples with satisfactory results.