Thermal degradation kinetic study of creatinol phosphate and model selection
- 1. Baoding University, College of Biochemical and Environment Engineering (China)
Description
The thermal behaviors of creatinol phosphate (COP) were carried out with thermogravimetric analysis instruments. The kinetic parameters, including the activation energy and the pre-exponential factor of the decomposition process for COP were calculated through Kissinger and Kissinger–Akahira–Sunose methods, and the thermal decomposition mechanism was also studied with Šatava–Šesták method and master plots procedure. The thermal degradation of COP proceeds through more complex and multi-step kinetics. The experimental thermal decomposition data for COP in the range of 0 < α < 0.2 can be most probably described with the three-dimensional diffusion model. The results provide basic data to further investigate thermal decomposition characteristics for the application of COP.
Additional details
Identifiers
Publishing Information
- Journal Title
- Journal of Thermal Analysis and Calorimetry
- Journal Volume
- 138
- Journal Issue
- 5
- Journal Page Range
- p. 3031-3037
- ISSN
- 1388-6150
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 51104615
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S36: MATERIALS SCIENCE;
- Descriptors DEI
- ACTIVATION ENERGY; COBALT PHOSPHIDES; DIFFUSION; KINETICS; PHOSPHATES; PYROLYSIS; THERMAL DEGRADATION; THERMAL GRAVIMETRIC ANALYSIS; THREE-DIMENSIONAL CALCULATIONS; THREE-DIMENSIONAL LATTICES
- Descriptors DEC
- CHEMICAL ANALYSIS; CHEMICAL REACTIONS; COBALT COMPOUNDS; CRYSTAL LATTICES; CRYSTAL STRUCTURE; DECOMPOSITION; ENERGY; GRAVIMETRIC ANALYSIS; OXYGEN COMPOUNDS; PHOSPHIDES; PHOSPHORUS COMPOUNDS; PNICTIDES; QUANTITATIVE CHEMICAL ANALYSIS; THERMAL ANALYSIS; THERMOCHEMICAL PROCESSES; TRANSITION ELEMENT COMPOUNDS
Optional Information
- Copyright
- Copyright (c) 2019 Akademiai Kiado, Budapest, Hungary