Published May 1989 | Version v1
Journal article Metadata-only

X-ray diffraction study of uranyl sulfate complexes with acetamide

Creators

  • 1. Kujbyshevskij Gosudarstvennyj Univ., Kuibyshev (USSR)

Description

X-ray diffraction study of UO2SO4xLx2H2O (1), UO2SO4x2Lx2H2O (2) and UO2SO4x3LxH2O (3) (L-acetamide) complexes, which crystals were prepared by slow evaporation at room temperature uranyl sulfate and acetamide aqueous solutions with a definite molar ratio, is carried out. The lattice parameters for (1) are: a=17.520; b=6.917; c=8.759 A; β=104.40 deg sp.gr. s2/mC2 or Cm; for (2): a=7.248; b=9.451; c=10.623 A; α=109.15; β=107.79; γ=74.55 deg; sp.gr. P1-bar; for (3): a=8.494; b=10.170; c=10.606 A; α=118.81; β=102.92; γ=90.10 deg; sp.gr. P1-bar. Peculiarities of crystal-structure transformations in acetamide and carbamide uranyl sulfate complexes with change of UO2SO4:L ratio (L-acetamide or carbamide) are discussed

Additional details

Additional titles

Original title (Russian)
Рентгенографическое исследование комплексов сульфата уранила с ацетамидом

Publishing Information

Journal Title
Zhurnal Neorganicheskoj Khimii
Journal Volume
34
Journal Issue
5
Series
Zh. Neorg. Khim.
Journal Page Range
1251-1255
ISSN
0044-457X
CODEN
ZNOKA

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
21009640
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Descriptors DEI
ACETAMIDE; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; CRYSTAL STRUCTURE; HYDRATES; LATTICE PARAMETERS; MONOCRYSTALS; QUANTITY RATIO; SPACE GROUPS; SULFATES; URANYL COMPLEXES; UREA
Descriptors DEC
ACTINIDE COMPLEXES; AMIDES; CARBONIC ACID DERIVATIVES; COMPLEXES; CRYSTALS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; OXYGEN COMPOUNDS; SULFUR COMPOUNDS; SYMMETRY GROUPS; SYNTHESIS; URANIUM COMPLEXES