Published 1972
| Version v1
Journal article
Nanosecond pulse radiolysis of acetone
Description
Spectra of the molecular ions of acetone, formed during liquid phase pulse radiolysis are reported. The kinetic features of the monomer-dimer cation equilibria of some aromatic hydrocarbon solutes have been obtained at a number of temperatures. Equilibrium constants and thermodynamic data are measured and their implications discussed. The data are compared with literature values for the analogous equilibria involving excited singlet monomers and excimers.
Additional details
Additional titles
- Subtitle (English)
- Kinetic and thermodynamic properties of some aromatic radical cations
Identifiers
- DOI
- 10.1039/f19726801278;
Publishing Information
- Journal Title
- Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
- Journal Volume
- 68
- Journal Issue
- 0
- Series
- J. Chem. Soc. (London), Faraday Trans., I.
- Journal Page Range
- 1278
- ISSN
- 0300-9599
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- United Kingdom
- INIS RN
- 4039923
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- ACETONE; AROMATICS; CATIONS; CHEMICAL REACTION KINETICS; DIMERS; EQUILIBRIUM; EXCITATION; EXCITED STATES; LIQUIDS; MOLECULES; MONOMERS; PULSED IRRADIATION; PULSES; RADIATION CHEMISTRY; RADICALS; RADIOLYSIS; SPECTRA; TEMPERATURE DEPENDENCE; THERMODYNAMIC PROPERTIES
- Descriptors DEC
- CHARGED PARTICLES; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; CHEMISTRY; DECOMPOSITION; ENERGY LEVELS; ENERGY-LEVEL TRANSITIONS; FLUIDS; IONS; IRRADIATION; KETONES; KINETICS; ORGANIC COMPOUNDS; PHYSICAL PROPERTIES; RADIATION EFFECTS; REACTION KINETICS
Optional Information
- Notes
- Updated automatically by Metadata and Full-Text Enrichment Agent