Published April 17, 2000 | Version v1
Journal article

Ground State Theory of δ-Pu

Description

Correlation effects are important for making predictions in the δ phase of Pu. Using a realistic treatment of the intra-atomic Coulomb correlations we address the long-standing problem of computing ground state properties. The equilibrium volume is obtained in good agreement with experiment when taking into account Hubbard U of the order 4 eV. For this U, the calculation predicts a 5f5 atomiclike configuration with L=5 , S=5/2 , and J=5/2 and shows a nearly complete compensation between spin and orbital magnetic moments. (c) 2000 The American Physical Society

Additional details

Publishing Information

Journal Title
Physical Review Letters
Journal Volume
84
Journal Issue
16
Journal Page Range
p. 3670-3673
ISSN
0031-9007
CODEN
PRLTAO

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
32059827
Subject category
S36: MATERIALS SCIENCE;
Resource subtype / Literary indicator
Numerical Data
Descriptors DEI
CRYSTAL STRUCTURE; ELECTRON CORRELATION; ELECTRON-ELECTRON INTERACTIONS; ELECTRONIC STRUCTURE; GROUND SOURCE HEAT PUMPS; HUBBARD MODEL; MAGNETIC MOMENTS; PHASE DIAGRAMS; PLUTONIUM; THEORETICAL DATA
Descriptors DEC
ACTINIDES; CORRELATIONS; CRYSTAL MODELS; DATA; DIAGRAMS; ELEMENTS; HEAT PUMPS; INFORMATION; INTERACTIONS; LEPTON-LEPTON INTERACTIONS; MATHEMATICAL MODELS; METALS; NUMERICAL DATA; PARTICLE INTERACTIONS; TRANSURANIUM ELEMENTS
Proposed descriptors and Free-text terms
density functional theory