Published January 1983
| Version v1
Journal article
A pulse radiolysis study of trapped electrons in aqueous ethylene glycol glasses
- 1. National Research Council of Canada, Ottawa, Ontario. Div. of Physics
Description
The yield and reaction kinetics of trapped electrons, esub(ir)sup(-) and esub(vis)sup(-), in several ethylene glycol/D2O glasses have been studied from 6-72 K by pulse radiolysis. An increased D2O concentration is believed to increase the concentration of IR-traps thereby leading to a greater G(esub(ir)sup(-)) and to decrease the concentration of VIS-traps thereby increasing the stability of esub(ir)sup(-). The yield and stability of esub(ir)sup(-) are also increased by lowering the temperature. A redetermination of epsilon(esub(ir)sup(-)) (1.3 x 104 M-1 cm-1 at 1800 nm) confirms earlier values
Additional details
Publishing Information
- Journal Title
- Can. J. Chem.
- Journal Volume
- 61
- Journal Issue
- 1
- Series
- Can. J. Chem.
- Journal Page Range
- 189-193
- ISSN
- 0008-4042
INIS
- Country of Publication
- Canada
- Country of Input or Organization
- Canada
- INIS RN
- 15020575
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- AQUEOUS SOLUTIONS; ELECTRON BEAMS; G VALUE; GLYCOLS; HEAVY WATER; INFRARED SPECTRA; LOW TEMPERATURE; PULSED IRRADIATION; TRAPPED ELECTRONS; ULTRALOW TEMPERATURE; VISIBLE SPECTRA
- Descriptors DEC
- ALCOHOLS; BEAMS; DISPERSIONS; ELECTRONS; ELEMENTARY PARTICLES; FERMIONS; HOMOGENEOUS MIXTURES; HYDROGEN COMPOUNDS; HYDROXY COMPOUNDS; IRRADIATION; LEPTON BEAMS; LEPTONS; MIXTURES; ORGANIC COMPOUNDS; OXYGEN COMPOUNDS; PARTICLE BEAMS; SOLUTIONS; SPECTRA; WATER