Published March 1, 1983 | Version v1
Journal article

M dependence in the analysis of NH3--He microwave double resonance experiments

  • 1. Department of Chemistry, George Mason University, Fairfax, Virginia 22030

Description

New close-coupled calculations of laboratory-frame, m-dependent cross sections for rotational excitation in NH3--He collisions are used to examine the validity of using degeneracy averaged values in the analysis of four-level double resonance experiments. It is found that the proper use of m-dependent cross sections and absorption probabilities produces only minor changes in the calculated δI/I and does not, therefore, resolve the discrepancies between theoretical and experimental values that were noted in previous studies

Additional details

Publishing Information

Journal Title
J. Chem. Phys.
Journal Volume
78
Journal Issue
5
Series
J. Chem. Phys.
Journal Page Range
2170-2174
ISSN
0021-9606