Published March 1, 1983
| Version v1
Journal article
M dependence in the analysis of NH3--He microwave double resonance experiments
Creators
- 1. Department of Chemistry, George Mason University, Fairfax, Virginia 22030
Description
New close-coupled calculations of laboratory-frame, m-dependent cross sections for rotational excitation in NH3--He collisions are used to examine the validity of using degeneracy averaged values in the analysis of four-level double resonance experiments. It is found that the proper use of m-dependent cross sections and absorption probabilities produces only minor changes in the calculated δI/I and does not, therefore, resolve the discrepancies between theoretical and experimental values that were noted in previous studies
Additional details
Publishing Information
- Journal Title
- J. Chem. Phys.
- Journal Volume
- 78
- Journal Issue
- 5
- Series
- J. Chem. Phys.
- Journal Page Range
- 2170-2174
- ISSN
- 0021-9606
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 14765484
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS;
- Descriptors DEI
- AMMONIA; ATOM-MOLECULE COLLISIONS; CROSS SECTIONS; EMISSION SPECTRA; EXCITATION; HELIUM; MICROWAVE SPECTRA; ROTATIONAL STATES
- Descriptors DEC
- ATOM COLLISIONS; COLLISIONS; ELEMENTS; ENERGY LEVELS; ENERGY-LEVEL TRANSITIONS; EXCITED STATES; HYDRIDES; HYDROGEN COMPOUNDS; MOLECULE COLLISIONS; NITROGEN COMPOUNDS; NITROGEN HYDRIDES; NONMETALS; RARE GASES; SPECTRA