Published July 4, 1979
| Version v1
Journal article
Syntheses and electronic structures of decamethylmanganocenes
- 1. Univ. of California, Berkeley
Description
The syntheses of [(C5(CH3)5)2Mn]PF6, (C5(CH3)5)2Mn, and Na[(C5(CH3)5)2Mn] are described. Magnetic susceptibility, infrared, electrochemical, NMR, and reactivity studies suggest the formulation of these complexes as low-spin 16-, 17-, and 18-electron planar metallocenes. EPR spectra of the neutral complex are consistent with the 2E/sub 2g/ configuration determined for other low-spin 17-electron metallocenes. 1 figure, 3 tables
Additional details
Publishing Information
- Journal Title
- J. Am. Chem. Soc.
- Journal Volume
- 101
- Journal Issue
- 14
- Series
- J. Am. Chem. Soc.
- Journal Page Range
- 3853-3857
- ISSN
- 0002-7863
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 11516713
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ELECTROCHEMISTRY; ELECTRONIC STRUCTURE; MAGNETIC SUSCEPTIBILITY; MANGANESE COMPLEXES; NUCLEAR MAGNETIC RESONANCE; SYNTHESIS
- Descriptors DEC
- COMPLEXES; MAGNETIC PROPERTIES; MAGNETIC RESONANCE; PHYSICAL PROPERTIES; RESONANCE; TRANSITION ELEMENT COMPLEXES