Published June 2005
| Version v1
Journal article
Ultraviolet photoelectron spectroscopy of multiple atoms encapsulated fullerenes
Creators
- 1. Faculty of Engineering, Chiba University, Chiba 263-8522 (Japan) and Graduate School of Science and Technology, Chiba University, Chiba 263-8522 (Japan)
- 2. Graduate School of Science and Technology, Chiba University, Chiba 263-8522 (Japan)
- 3. Faculty of Engineering, Chiba University, Chiba 263-8522 (Japan)
- 4. Research Center for Material Science, Nagoya University, Nagoya 464-8602 (Japan)
- 5. Institute for Molecular Science, Okazaki 444-8585 (Japan)
- 6. Graduate School of Science, Nagoya University, Nagoya 464-8602 (Japan)
Description
Ultraviolet photoelectron spectra (UPS) of metallofullerenes with multiple atoms inside the cage, Ti2-C80, Ti2-C84 and Y2C2-C82, have been measured with a synchrotron orbital radiation light source. The spectra were compared with those of other metallofullerenes. Spectral onsets of these metallofullerenes are 0.7-0.8 eV, which is close to those of group II metal atom encapsulated metallofullerenes but much larger than those of other group III mono-metal atom encapsulated ones. The spectra are compared with molecular orbital calculation to estimate the amounts of transferred electrons and the cage structure
Additional details
Identifiers
- DOI
- 10.1016/j.elspec.2005.01.069;
- PII
- S0368-2048(05)00043-5;
Publishing Information
- Journal Title
- Journal of Electron Spectroscopy and Related Phenomena
- Journal Volume
- 144-147
- Journal Page Range
- p. 239-242
- ISSN
- 0368-2048
- CODEN
- JESRAW
Conference
- Title
- 14. international conference on vacuum ultraviolet radiation physics
- Acronym
- VUV 14
- Dates
- 19-23 Jul 2004
- Place
- Cairns (Australia)
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 37039742
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS;
- Resource subtype / Literary indicator
- Conference
- Descriptors DEI
- ATOMS; ELECTRON EMISSION; ELECTRON SPECTRA; ELECTRON TRANSFER; ELECTRONIC STRUCTURE; EV RANGE; FULLERENES; LIGHT SOURCES; METALS; MOLECULAR ORBITAL METHOD; PHOTOELECTRON SPECTROSCOPY; TITANIUM COMPOUNDS; ULTRAVIOLET RADIATION; YTTRIUM COMPOUNDS
- Descriptors DEC
- CALCULATION METHODS; CARBON; ELECTROMAGNETIC RADIATION; ELECTRON SPECTROSCOPY; ELEMENTS; EMISSION; ENERGY RANGE; NONMETALS; RADIATION SOURCES; RADIATIONS; SPECTRA; SPECTROSCOPY; TRANSITION ELEMENT COMPOUNDS
Optional Information
- Copyright
- Copyright (c) 2005 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.