Published January 17, 2019
| Version v1
Journal article
Latex-state 13C-NMR spectroscopy for poly(butyl acrylate)
- 1. Nagaoka University of Technology, Department of Material Science and Technology (Japan)
- 2. Tokyo College, Department of Mechanical Engineering, National Institute of Technology (Japan)
Description
The resolution and the relaxation time of poly(butyl acrylate) in latex-state 13C-NMR spectroscopy are associated with local motions of the polymer in a dispersoid. Latexes were prepared by emulsion polymerization of butyl acrylate with ammonium persulfate. The latex-state 13C-NMR spectra were measured at 323–353 K with a spectrometer operating at 399.7 and 100.4 MHz for 1H and 13C, respectively. The half width of the latex-state 13C-NMR spectrum depends on the temperature. The half width and the spin-spin relaxation time, T2, are superimposed onto the master curve with a reference temperature, TX.
Additional details
Identifiers
Publishing Information
- Journal Title
- Colloid and Polymer Science (Print)
- Journal Volume
- 297
- Journal Issue
- 1
- Journal Page Range
- p. 133-139
- ISSN
- 0303-402X
- CODEN
- CPMSB6
INIS
- Country of Publication
- Germany
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 54084891
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S36: MATERIALS SCIENCE;
- Descriptors DEI
- ACRYLATES; CARBON 13; EMULSIONS; LATEX; MHZ RANGE; NUCLEAR MAGNETIC RESONANCE; PERSULFATES; POLYMERIZATION; RELAXATION TIME; SPECTROMETERS; SPECTROSCOPY; SPIN-SPIN RELAXATION
- Descriptors DEC
- CARBON ISOTOPES; CARBOXYLIC ACID SALTS; CHEMICAL REACTIONS; COLLOIDS; DISPERSIONS; ELASTOMERS; EVEN-ODD NUCLEI; FREQUENCY RANGE; ISOTOPES; LIGHT NUCLEI; MAGNETIC RESONANCE; MEASURING INSTRUMENTS; NUCLEI; ORGANIC COMPOUNDS; ORGANIC POLYMERS; OXYGEN COMPOUNDS; POLYMERS; RELAXATION; RESONANCE; RUBBERS; STABLE ISOTOPES; SULFUR COMPOUNDS
Optional Information
- Copyright
- Copyright (c) 2019 Springer-Verlag GmbH Germany, part of Springer Nature