Published May 1976 | Version v1
Journal article

Thermodynamics of ion exchange on sulphonated copolymers of styrene and divinyl benzene

  • 1. AN Belorusskoj SSR, Minsk. Inst. Obshchej i Neorganicheskoj Khimii

Description

The free energies, enthalpies and entropies of the exchange of alkaline earth metal ions for H+ and Li+ on KRSx8P sulphostyrene resin have been calculated and it has been established that the values of ΔG0 and ΔH0 increase in absolute magnitude with increase in crystallographic radius, while the values of YΔS0 are almost the same for all the exchange processes. An anomalously strong interaction with the resin relative to other alkaline earth metal ions is characteristic of the Ba2+ ion

Additional details

Additional titles

Subtitle (English)
18. Thermodynamic functions of the exchange of alkaline earth metal ions for hydrogen and lithium ions
Original title (Russian)
Термодинамика ионного обмена на сульфированных сополимерах стирола и дивинилбензола
Original subtitle (Russian)
18. Termodinamicheskie funktsii obmena ionov shchelochnozemel'nykh metallov na iony H"+ i Li"+.

Publishing Information

Journal Title
Zh. Fiz. Khim.
Journal Volume
50
Journal Issue
5
Series
Zh. Fiz. Khim.
Journal Page Range
1140-1143

Optional Information

Notes
For English translation see the journal Russ. J. Phys. Chem.