Published June 15, 1983
| Version v1
Journal article
Frequency dependent polarizabilities for the ground state of H2, HD, and D2
Creators
- 1. Department of Chemistry, A. Mickiewicz University, Grunwaldzka 6, 60-780 Poznan, Poland
Description
A variation-perturbation method has been employed to calculate the dynamic dipole polarizability for the ground state of the hydrogen molecule. The explicit correlated electronic wave functions were used. The averaged values of α(#betta#) and #betta#(#betta#) for several vibration-rotation states of HD and D2 are presented. Similar values for H2 have also been calculated and were used to test the efficiency of the method and the validity of the assumption applied in the present calculation. The agreement of the present theoretical results with the existing experimental data is found to be satisfactory
Additional details
Publishing Information
- Journal Title
- J. Chem. Phys.
- Journal Volume
- 78
- Journal Issue
- 12
- Series
- J. Chem. Phys.
- Journal Page Range
- 7252-7259
- ISSN
- 0021-9606
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 14780814
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS;
- Descriptors DEI
- DEUTERIUM; FREQUENCY DEPENDENCE; GROUND STATES; HYDRIODIC ACID; HYDROGEN; POLARIZABILITY
- Descriptors DEC
- ELECTRICAL PROPERTIES; ELEMENTS; ENERGY LEVELS; HALOGEN COMPOUNDS; HYDROGEN COMPOUNDS; HYDROGEN ISOTOPES; INORGANIC ACIDS; IODINE COMPOUNDS; ISOTOPES; LIGHT NUCLEI; NONMETALS; NUCLEI; ODD-ODD NUCLEI; PHYSICAL PROPERTIES; STABLE ISOTOPES