Published June 15, 1983 | Version v1
Journal article

Frequency dependent polarizabilities for the ground state of H2, HD, and D2

  • 1. Department of Chemistry, A. Mickiewicz University, Grunwaldzka 6, 60-780 Poznan, Poland

Description

A variation-perturbation method has been employed to calculate the dynamic dipole polarizability for the ground state of the hydrogen molecule. The explicit correlated electronic wave functions were used. The averaged values of α(#betta#) and #betta#(#betta#) for several vibration-rotation states of HD and D2 are presented. Similar values for H2 have also been calculated and were used to test the efficiency of the method and the validity of the assumption applied in the present calculation. The agreement of the present theoretical results with the existing experimental data is found to be satisfactory

Additional details

Publishing Information

Journal Title
J. Chem. Phys.
Journal Volume
78
Journal Issue
12
Series
J. Chem. Phys.
Journal Page Range
7252-7259
ISSN
0021-9606