Published August 1997 | Version v1
Journal article

High temperature Moessbauer studies of 57Fe: YSr2Cu3O7 related compounds containing oxyanions

  • 1. Univ. Nacional Mayor de San Marcos, Facultad de Ciencias Fisicas, Lima (Peru)
  • 2. Centro Brasileiro de Pesquisas Fisicas, Rio de Janeiro, RJ (Brazil)

Description

Oxyanion substitutions at the copper sites can stabilize the Ba free phase YSr2Cu3O7 and allow synthesis to occur under ambient conditions. Here we report in situ 57Fe Moessbauer spectroscopy experiments done in Y-Sr-Cu-O related oxides containing sulphate (SO42-), phosphate (PO43-) and borate (BO33-), in the temperature range 300 K≤T≤723 K. From the results obtained it has been possible to study the kinetics of oxygen loss, as well as the temperature dependence of the Fe species. (orig.)

Additional details

Publishing Information

Journal Title
Hyperfine Interactions
Journal Volume
110
Journal Issue
1-2
Journal Page Range
p. 17-22.
ISSN
0304-3843
CODEN
HYINDN

Conference

Title
5. Latin American conference on applications of the Moessbauer effect (LACAME-5).
Dates
9-14 Sep 1996.
Place
Cusco (Peru).

Optional Information

Notes
10 refs.