Published September 2014 | Version v1
Journal article Metadata-only

Solvent extraction of Mo(V) and Mo(VI) from hydrochloric acid into Aliquat 336 chloroform solution

Creators

  • 1. Osaka University, Toyonaka Osaka (Japan). Graduate School of Science
  • 2. Niigata University, Niigata Niigata (Japan). Faculty of Science
  • 3. Radioisotope Research Center, Osaka University, Suita Osaka (Japan)

Description

Solvent extraction of macro amounts of Mo(V) and Mo(VI) from HCl using Aliquat 336 in chloroform was performed for the electrochemistry of Sg. The extraction reaction attained equilibrium with a shaking time of 10 s in higher than 8 M HCl. The D values of Mo(V) obtained by the electrochemical reduction of Mo(VI) were in good agreement with those obtained by the extraction of MoCl5, and the D values of Mo(V) were higher than those of Mo(VI). These results suggested that the reduction behavior of Sg might be studied by electrochemical reduction combined with the present solvent extraction. (author)

Additional details

Publishing Information

Journal Title
Journal of Radioanalytical and Nuclear Chemistry
Journal Volume
301
Journal Issue
3
Journal Page Range
p. 751-756
ISSN
0236-5731
CODEN
JRNCDM

INIS

Country of Publication
Hungary
Country of Input or Organization
Hungary
INIS RN
45082024
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
CHLOROFORM; HYDROCHLORIC ACID; MOLYBDENUM; SOLVENT EXTRACTION
Descriptors DEC
CHLORINATED ALIPHATIC HYDROCARBONS; CHLORINE COMPOUNDS; ELEMENTS; EXTRACTION; HALOGEN COMPOUNDS; HALOGENATED ALIPHATIC HYDROCARBONS; HYDROGEN COMPOUNDS; INORGANIC ACIDS; INORGANIC COMPOUNDS; METALS; ORGANIC CHLORINE COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; REFRACTORY METALS; SEPARATION PROCESSES; TRANSITION ELEMENTS

Optional Information

Notes
40 refs.