Published July 1, 1987 | Version v1
Journal article

Electron thermalization distances and free ion yields in liquid nitrogen from 77 K to near T/sub c/

  • 1. Department of Chemistry, University of Alberta, Edmonton T6G 2G2, Canada

Description

The free ion yield in x-irradiated liquid nitrogen at zero applied field strength increases from G0/sub fl/ = 0.0034 ion pairs/100 eV at 77.1 K to 0.043 at 123.7 K, while the density-normalized thermalization distance of the secondary electrons increases from b/sub E//sub P/d = 4.4 x 10-6 to 5.6 x 10-6 kg/m2. The ratio of the G/sup E//sub f//sub i/ values at 123.7 and 77.1 K decreases from 13 at E = 0 to 3.1 at E = 5.2 MV/m. Yields calculated from the extended Onsager model agree with the measured values only when the electron thermalization distance distribution is assumed to be exponential with an added power tail (YEP): F(y) = YE, 0<(y-y0)<3.5b/sub E//sub P/; F(y) = YE+0.74b2/sub E//sub P//(y-y0)3, (y-y0)>3.5b/sub E//sub P/; where YE = b/sup -1//sub E//sub P/ exp[(y0-y)/b/sub E//sub P/], y>y0. The electron thermalization process in liquid nitrogen appears to be truncated by electron capture to form an anion

Additional details

Publishing Information

Journal Title
J. Chem. Phys.
Journal Volume
87
Journal Issue
1
Series
J. Chem. Phys.
Journal Page Range
319-324
ISSN
0021-9606
CODEN
JCPSA