Published November 2008 | Version v1
Journal article

Photosensitive properties of metal-containing polydisalicylidene azomethines

  • 1. Russian Academy of Sciences, Ioffe Physicotechnical Institute (Russian Federation)
  • 2. Russian Academy of Science, Institute of Macromolecular Compounds (Russian Federation)

Description

Photosensitive properties of new metal-containing polydisalicylidene azomethines were studied. It was shown that polymer properties are controlled by the nature of the metal atom (its electron affinity energy Aa and ionic radius ri) included in 'nonclassical' polyconjugation. The photosensitivity S0.1 of studied polymers is ∼105cm2/J, and the quantum yield of free-carrier photogeneration is η ∼ 0.10-0.15, which corresponds to the level of organometallic complexes that have found application in optoelectronics.

Additional details

Identifiers

Publishing Information

Journal Title
Semiconductors
Journal Volume
42
Journal Issue
11
Journal Page Range
p. 1338-1341
ISSN
1063-7826
CODEN
SMICES

INIS

Country of Publication
United States
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
41006151
Subject category
S36: MATERIALS SCIENCE;
Descriptors DEI
AFFINITY; AZO COMPOUNDS; COMPLEXES; ORGANIC POLYMERS; ORGANOMETALLIC COMPOUNDS; PHOTOSENSITIVITY
Descriptors DEC
ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; POLYMERS; SENSITIVITY

Optional Information

Copyright
Copyright (c) 2008 Pleiades Publishing, Ltd.