Published December 2013 | Version v1
Journal article

Structural, magnetic and electronic transport studies of RAgSn2 compounds (R = Y, Tb, Dy, Ho and Er) with Cu3Au-type

  • 1. Department of Inorganic Chemistry, Ivan Franko Lviv National University, Kyryl and Mephodiy Street, Lviv (Ukraine)
  • 2. Department of Materials Engineering and Applied Physics, Lviv Polytechnic National University, Ustyyanovycha Street, Lviv (Ukraine)
  • 3. Institute of Physics, Jagiellonian University, Reymonta , Krakow (Poland)
  • 4. Institut Néel, CNRS et Université Joseph Fourier, BP, F- Grenoble (France)

Description

RAgSn2 compounds, where R = Y, Tb, Dy, Ho and Er, were synthesized by arc-melting and subsequent annealing at 870 K. The formation of cubic phases with Cu3Au-type structure (space group Pm3m) was studied. Magnetic property measurements showed that in paramagnetic state, the compounds with magnetic rare- earth atoms are Curie-Weiss paramagnets and order antiferromagnetically at low temperatures. YAgSn2 is a Pauli paramagnet in 100-300 K temperature range. The electrical properties of RAgSn2 compounds were investigated by means of electrical resistivity and Seebeck coefficient measurements in 4.2-300 K temperature range. All investigated compounds exhibit metallic type of conductivity. Electronic structure calculations based on full potential linearized augmented plane wave (FLAPW) method is also carried out to probe the magnetic and electronic structures of RAgSn2 compounds. Comparisons between experimental data and calculations are discussed. (author)

Additional details

Publishing Information

Journal Title
Bulletin of Materials Science
Journal Volume
36
Journal Issue
7
Journal Page Range
p. 1247-1253
CODEN
BUMSDW

Optional Information

Notes
38 refs., 10 figs., 1 tab.