Published March 1987
| Version v1
Journal article
Low-temperature chemiluminescence
Description
Literary data on chemiluminescent (CL) reactions in cryogenic matrices of nitrogen and inert gases are systematized and genralized. Trends in developments of investigations in the field of low-temperature CL are traced. Reaction of uranium(4) sulphate complex oxidation by xenon difluoride in H2SO4 is considered in detail as the most typical one for this type of CL reactions and at the same time - as the one, possessing its own peculiarities. Irregularly high effect of the solvent deuteration, resulting both in sufficient change of temperature dependence of CL intensity and the differential thermal analysis curve, produced synchronously under heating of a sample, quick frozen up to 77 K, is indicated
Additional details
Additional titles
- Original title (Russian)
- Низкотемпературная хемилюминесценция
Publishing Information
- Journal Title
- Izv. Akad. Nauk SSSR, Ser. Fiz.
- Journal Volume
- 51
- Journal Issue
- 3
- Series
- Izv. Akad. Nauk SSSR, Ser. Fiz.
- Journal Page Range
- 568-575
- ISSN
- 0367-6765
- CODEN
- IANFA
Conference
- Title
- 2. All-union conference on chemiluminescence.
- Dates
- May 1986.
- Place
- Ufa (USSR).
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- USSR
- INIS RN
- 19016670
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Resource subtype / Literary indicator
- Conference
- Descriptors DEI
- CHEMICAL REACTION KINETICS; CHEMILUMINESCENCE; DEUTERATION; LOW TEMPERATURE; MATRIX ISOLATION; OXIDATION; SULFATES; SULFURIC ACID; TEMPERATURE DEPENDENCE; URANIUM COMPLEXES; XENON FLUORIDES
- Descriptors DEC
- ACTINIDE COMPLEXES; CHEMICAL REACTIONS; COMPLEXES; EMISSION; FLUORIDES; FLUORINE COMPOUNDS; HALIDES; HALOGEN COMPOUNDS; HYDROGEN COMPOUNDS; INORGANIC ACIDS; INORGANIC COMPOUNDS; KINETICS; LUMINESCENCE; OXYGEN COMPOUNDS; PHOTON EMISSION; RARE GAS COMPOUNDS; REACTION KINETICS; SULFUR COMPOUNDS; XENON COMPOUNDS