Cu2O/Fe3O4/MIL-101(Fe) nanocomposite as a highly efficient and recyclable visible-light-driven catalyst for degradation of ciprofloxacin

Nowadays, the widespread production and use of antibiotics have increased their presence in wastewater systems, posing a potential threat to the environment and human health. The development of advanced materials for treating antibiotics in wastewater has always received special attention. This study aimed to synthesize a novel Cu₂O/Fe₃O₄/MIL-101(Fe) nanocomposite and use it to degrade ciprofloxacin (CIP) antibiotics in an aqueous solution under visible light irradiation. The optical, structural, and morphological attributes of the developed nanocomposite were analyzed by XRD, FTIR, FE-SEM, TGA, DRS, BET, VSM, and UV–Vis techniques. Optimum circumstances for CIP photocatalytic degradation were acquired in 0.5 g L⁻¹ of catalyst dosage, pH of 7, and CIP concentration of 20 mg L⁻¹. The degradation efficiency was achieved 99.2% after 105 min of irradiation in optimum circumstances. The chemical trapping experiments confirmed that hydroxyl and superoxide radicals significantly contributed to the CIP degradation process. The results of this study indicated that Cu₂O/Fe₃O₄/MIL-101(Fe) nanocomposite was a highly stable photocatalyst that could effectively remove antibiotics from aqueous solutions. The CIP degradation efficiency only decreased by 6% after five cycles, indicating the excellent recyclability of Cu₂O/Fe₃O₄/MIL-101(Fe) nanocomposites.