Published September 20, 1989
| Version v1
Journal article
35Cl NQR spectra of complexes of SnCl4 with the aryl phosphorodichloridates XnC6H5-nOPOCl2
- 1. Irkutsk Inst. of Organic Chemistry (USSR)
Description
By the 35Cl NQR method it was shown that in the interaction of equimolecular amounts of XnC6H5-nOPOCl2 and SnCl4 trigonal-bipyramidal complexes are formed, [X= CH3, Cl] but at a reactant ratio of 2:1 the products are octahedral complexes. In both cases the electron-donor center is the phosphoryl oxygen atom. The shift in the NQR frequency of the chlorine atom of the POCl2 group in the formation of octahedral complexes is usually somewhat greater than in the formation of trigonal-bipyramidal complexes
Additional details
Publishing Information
- Journal Title
- Journal of General Chemistry of the USSR (English Translation)
- Journal Volume
- 59
- Journal Issue
- 4
- Series
- J. Gen. Chem. USSR (Engl. Transl.).
- Journal Page Range
- 656-659
- ISSN
- 0022-1279
- CODEN
- JGCHA
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 23029352
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Resource subtype / Literary indicator
- Numerical Data, Translation
- Descriptors DEI
- AROMATICS; COMPLEXES; EXPERIMENTAL DATA; MOLECULAR STRUCTURE; NUCLEAR QUADRUPOLE RESONANCE; ORGANIC CHLORINE COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; ORGANIC PHOSPHORUS COMPOUNDS; PHOSPHORUS CHLORIDES; TIN CHLORIDES
- Descriptors DEC
- CHLORIDES; CHLORINE COMPOUNDS; DATA; HALIDES; HALOGEN COMPOUNDS; INFORMATION; NUMERICAL DATA; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; PHOSPHORUS COMPOUNDS; RESONANCE; TIN COMPOUNDS; TIN HALIDES
Optional Information
- Notes
- (English). Cover-to-cover Translation of Zhurnal Obshchei Khimii (USSR). Cover-to-cover translation of Zhurnal Obshchej Khimii (USSR).