Published May 5, 2008 | Version v1
Journal article

Dipole-induced, first-order phase transitions of nano-rod monolayers

  • 1. Department of Mathematics and Institute for Advanced Materials, University of North Carolina at Chapel Hill, Chapel Hill, NC 27599-3250 (United States)
  • 2. Department of Mathematics, Florida State University, Tallahassee, FL 32306 (United States)
  • 3. Department of Mathematics and Statistics, Old Dominion University, Norfolk, VA 23529 (United States)

Description

The isotropic-nematic transition of nano-rod monolayers with fore-aft symmetry is second order, in stark contrast to the first-order phase transition explained by Onsager [L. Onsager, Ann. (N.Y.) Acad. Sci. 51 (1949) 627] for rods in three dimensions. Here we show that the coupling of a dipole potential to excluded volume is sufficient to re-instate a first-order phase transition of rods confined to two dimensions

Availability note (English)

Available from http://dx.doi.org/10.1016/j.physleta.2008.01.087

Additional details

Identifiers

DOI
10.1016/j.physleta.2008.01.087;
PII
S0375-9601(08)00195-3;

Publishing Information

Journal Title
Physics Letters. A
Journal Volume
372
Journal Issue
19
Journal Page Range
p. 3484-3487
ISSN
0375-9601
CODEN
PYLAAG

INIS

Country of Publication
Netherlands
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
40044004
Subject category
S71: CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS;
Descriptors DEI
COUPLING; DIPOLES; LAYERS; NANOSTRUCTURES; PHASE TRANSFORMATIONS; POTENTIALS; RODS; SYMMETRY
Descriptors DEC
MULTIPOLES

Optional Information

Copyright
Copyright (c) 2008 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.