Published July 1997 | Version v1
Journal article Metadata-only

Formation of paramagnetic centers during irradiation of potassium perchlorate-thallium perchlorate solid solutions

Creators

  • 1. Kemerovskij Gosudarstvennyj Univ., (Russian Federation)

Description

Paramagnetic centres in γ-irradiated solid solution of KClO4-TlClO4 have been identified. It is ascertained that the change in their nature and formation efficiency correlates with the change in the anion local surrounding. In the framework of the mechanism suggested the exprimentally obtained dependence of the paramagnetic centres radiation-chemical yield on Tl+ concentration has been quantitatively described

Additional details

Additional titles

Original title (Russian)
Образование парамагнитных центров при облучении твердого раствора перхлорат калия-перхлорат таллия

Publishing Information

Journal Title
Khimiya Vysokikh Ehnergij
Journal Volume
31
Journal Issue
4
Journal Page Range
p. 267-269.
ISSN
0023-1193
CODEN
KHVKAO

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
29014808
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Descriptors DEI
CHEMICAL REACTION KINETICS; CONCENTRATION RATIO; DOSE RATES; ELECTRON SPIN RESONANCE; G VALUE; GAMMA RADIATION; POTASSIUM PERCHLORATES; RADIATION DOSES; RADIOLYSIS; SOLID SOLUTIONS; THALLIUM COMPOUNDS
Descriptors DEC
ALKALI METAL COMPOUNDS; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; CHLORINE COMPOUNDS; DECOMPOSITION; DISPERSIONS; ELECTROMAGNETIC RADIATION; HALOGEN COMPOUNDS; HOMOGENEOUS MIXTURES; IONIZING RADIATIONS; KINETICS; MAGNETIC RESONANCE; MIXTURES; OXYGEN COMPOUNDS; PERCHLORATES; POTASSIUM COMPOUNDS; RADIATION EFFECTS; RADIATIONS; REACTION KINETICS; RESONANCE; SOLUTIONS

Optional Information

Notes
7 refs., 2 figs.