Published 1982
| Version v1
Journal article
Vibronic effects and structural nonrigidity in complexes μ-HM2(CO)10- with M=Cr, Mo, W
- 1. AN SSSR, Moscow
- 2. AN SSSR, Moscow. Inst. Obshchej i Neorganicheskoj Khimii
Description
Adiabatic potential for the μ-HM2(CO)10- (M=Cr, Mo, W) binuclear complexes is found on the base of the Young-Teller pseudoeffect [Et4N]+ and (Ph3P)+ serve as cations in the complexes considered. It is shown, that unusual geometry of the complexes with a hydrogen bridge could be explained by a dynamical character of the pseudoeffect in these complexes
Additional details
Additional titles
- Original title (Russian)
- Вибронные эффекты и структурная нежесткость в комплексах μ-HM
Publishing Information
- Journal Title
- Dokl. Akad. Nauk SSSR
- Journal Volume
- 266
- Journal Issue
- 2
- Series
- Dokl. Akad. Nauk SSSR.
- Journal Page Range
- 388-391
- ISSN
- 0002-3264
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- USSR
- INIS RN
- 14805180
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ANIONS; CARBONYLS; CRYSTAL STRUCTURE; HYDROGEN COMPLEXES; MOLECULAR STRUCTURE; MOLYBDENUM COMPLEXES; STRUCTURAL CHEMICAL ANALYSIS; TUNGSTEN COMPLEXES
- Descriptors DEC
- CHARGED PARTICLES; COMPLEXES; IONS; TRANSITION ELEMENT COMPLEXES