Published December 1986 | Version v1
Journal article Metadata-only

Solubility of alkali, alkaline earth metals and magnesium in anhydrous hydrogen peroxide

Creators

  • 1. AN SSSR, Chernogolovka. Inst. Novykh Khimicheskikh Problem

Description

Solubility of perchlorates of alkali, alkaline earth metals and magnesium in anhydrous N2O2 is investigated isothermally at 0 deg C. Solubility (in g of salt per 100 g of solvent at 0 deg C) constitutes for LiClO4 - 62.3; NaClO4 - 42.12; KClO4 - 3.52; RbClO4 - 4.73; CsClO4 - 15.34; Mg(ClO4)2 - 70.1; Ca(ClO4)2 - 97.7; Sr(ClO4)2 - 113.3. Calcium and strontium perchlorates are crystallized from H2O2 solutions in solvate form Ca(ClO4)2x2H2O2 and Sr(ClO4)2xH2O2. Lithium and magnesium perchlorates form not very stable solvates which composition can't be determined. Sodium, potassium, rubidium and cesium perchlorates are isolated from hydrogen peroxide solutions in nonsolvated state

Additional details

Additional titles

Original title (Russian)
Растворимост' перхлоратов щелочных, щелочноземельных металлов и магния в безводной перекиси водорода

Publishing Information

Journal Title
Zh. Neorg. Khim.
Journal Volume
31
Journal Issue
12
Series
Zh. Neorg. Khim.
Journal Page Range
3213-3215
ISSN
0044-457X
CODEN
ZNOKA

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
18072182
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ALKALI METAL COMPOUNDS; ALKALINE EARTH METAL COMPOUNDS; CRYSTALLIZATION; HYDROGEN PEROXIDE; MEDIUM TEMPERATURE; PERCHLORATES; SOLUBILITY; SOLVATION
Descriptors DEC
CHLORINE COMPOUNDS; HALOGEN COMPOUNDS; HYDROGEN COMPOUNDS; OXYGEN COMPOUNDS; PEROXIDES; PHASE TRANSFORMATIONS

Optional Information

Notes
For English translation see the journal Russian Journal of Inorganic Chemistry (UK).