Published 1995
| Version v1
Journal article
New pyridiniumchlorometallate compounds of the rare earth elements
Description
Reaction of the rare earth chlorides with pyridinium chloride in tetrahydrofuran (THF) under anhydrous conditions gave nearly insoluble precipitates of the composition (pyH)3RECl6·THF (RE=La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Y, Er, Tm, Yb, and Lu). They were characterized by chemical analysis and IR spectroscopy; decomposition in vacuo was studied. yielding the hithero unknown complexes (pyH)3RECl6 (RE=La, Ce, Pr, Sm, Tb, Ho, Y, Tm, and Lu). (author)
Additional details
Publishing Information
- Journal Title
- Monatshefte fuer Chemie
- Journal Volume
- 126
- Journal Page Range
- p. 687-694.
- ISSN
- 0026-9247
- CODEN
- MOCHAP
INIS
- Country of Publication
- Austria
- Country of Input or Organization
- Austria
- INIS RN
- 27021393
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CHLORIDES; INFRARED SPECTRA; PYRIDINE; RARE EARTH COMPLEXES
- Descriptors DEC
- AZINES; CHLORINE COMPOUNDS; COMPLEXES; HALIDES; HALOGEN COMPOUNDS; HETEROCYCLIC COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; PYRIDINES; SPECTRA