Published October 2010
| Version v1
Journal article
Vibrational Spectra of Distorted Structure Molecules by Using Lie Algebraic Techniques: an Application to Copper and Magnesium Octaethyl Porphyrin
Creators
- 1. School of Sciences and Humanities, Sri Viveka Institute of Technology (SVIT), Madalavari Gudem, Nunna, Krihna District-521212 (India)
Description
Using a U (2) algebraic model the fundamental stretching vibrations of copper octaethyl porphyrin and magnesium octaethyl porphyrin are calculated for 24 vibrational bands. The locality parameter ξ confirms the highly local behavior of the stretching modes of these porphyrin molecules. The model Hamiltonian so constructed appears to describe the vibrational energy levels accurately
Availability note (English)
Available from http://dx.doi.org/10.1088/0256-307X/27/10/103301Additional details
Identifiers
Publishing Information
- Journal Title
- Chinese Physics Letters
- Journal Volume
- 27
- Journal Issue
- 10
- Journal Page Range
- [4 p.]
- ISSN
- 0256-307X
- CODEN
- CPLEEU
INIS
- Country of Publication
- China
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 45000046
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS;
- Descriptors DEI
- COPPER COMPOUNDS; HAMILTONIANS; LOCALITY; MAGNESIUM COMPOUNDS; MOLECULAR STRUCTURE; MOLECULES; PORPHYRINS; U-2 GROUPS; VIBRATIONAL STATES
- Descriptors DEC
- ALKALINE EARTH METAL COMPOUNDS; CARBOXYLIC ACIDS; ENERGY LEVELS; EXCITED STATES; HETEROCYCLIC ACIDS; HETEROCYCLIC COMPOUNDS; LIE GROUPS; MATHEMATICAL OPERATORS; ORGANIC ACIDS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; QUANTUM OPERATORS; SYMMETRY GROUPS; TRANSITION ELEMENT COMPOUNDS; U GROUPS