Published September 1994 | Version v1
Journal article

Chemical shift of X-ray lines of uranium L-series at 5f-electrons removal (facsimile of 5f-electrons)

  • 1. RAN, Sankt-Peterburgskij Inst. Yadernoj Fiziki im. B.P. Konstantinova, Gatchina (Russian Federation)

Description

Shifts of the uranium L-series five X-ray lines for UF4-UF3 its ion compound pair are measured experimentally. A good correspondence with theoretical calculations using Dirac-Fock method in the assumption, that 5f-electron participates in the formation of chemical bond, is shown. 5 refs.; 1 fig

Additional details

Additional titles

Original title (Russian)
Химическое смещение рентгеновских линий Л-серии урана при удалении 5f-ьхлектрона (факсимиле 5f-электрона)

Publishing Information

Journal Title
Fizika Tverdogo Tela
Journal Volume
36
Journal Issue
9
Journal Page Range
p. 2729-2731.
ISSN
0367-3294
CODEN
FTVTAC

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
26052068
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Descriptors DEI
CHEMICAL BONDS; CHEMICAL SHIFT; ELECTRONIC STRUCTURE; URANIUM FLUORIDES; VALENCE; X-RAY SPECTRA
Descriptors DEC
ACTINIDE COMPOUNDS; FLUORIDES; FLUORINE COMPOUNDS; HALIDES; HALOGEN COMPOUNDS; SPECTRA; URANIUM COMPOUNDS