Published 1997 | Version v1
Journal article Metadata-only

Reaction of cyclopentadienyllutetiumanthracenide with azobenzene. Synthesis, molecular and crystal structure and dynamic behavior in solution of binuclear complex [C5H5(THF)Lu(μ-η2:η2-PhN-NPh)]2(THF)2

Creators

  • 1. GNTs RF Nauchno-Issledovatel'skij Fiziko-Khimicheskij Inst. im. L.Ya. Karpova, Moskva (Russian Federation)
  • 2. Inst. Ehlementorganicheskikh Soedinenij im. A.N. Nesmeyanova RAN , Moskva (Russian Federation)
  • 3. Vysshij Khimicheskij Kolledzh RAN, Moskva (Russian Federation)

Description

Reaction of cyclopentadienyllutetiumanthacenide C5H5Lu(C14H10)2-(THF)2 (1) with azobenzene resulting in binuclear complex [C5H5(THF)Lu(μ-η2:η2-PhN-NPh)]2(THF)2 (2) has been investigated. The structure of complex has been studied by X-ray method. The dynamic behavior of complex 2 in solution has been investigated by 1H NMR spectroscopy in THF-d8 solution in the temperature range of 265-330 K. (author)

Additional details

Additional titles

Original title (Russian)
Реакция циклопентадиениллютецийантраценида с азобензолом. Синтез, молекулярная и кристаллическая структура и динамическое поведение в раствор е биядерного комплекса [C

Publishing Information

Journal Title
Izvestiya Akademii Nauk. Rossijskaya Akademiya Nauk. Seriya Khimicheskaya
Journal Issue
no.9
Journal Page Range
p. 1667-1671.
ISSN
1026-3500
CODEN
IASKEA

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
29015916
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
AZO COMPOUNDS; BOND ANGLE; BOND LENGTHS; CHEMICAL PREPARATION; CYCLOPENTADIENE; LUTETIUM COMPLEXES; MOLECULAR STRUCTURE; NMR SPECTRA; PROTONS; TETRAHYDROFURAN
Descriptors DEC
ALKENES; BARYONS; CATIONS; CHARGED PARTICLES; COMPLEXES; CYCLOALKENES; DIENES; ELEMENTARY PARTICLES; FERMIONS; FURANS; HADRONS; HETEROCYCLIC COMPOUNDS; HYDROCARBONS; HYDROGEN IONS; HYDROGEN IONS 1 PLUS; IONS; NUCLEONS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; POLYENES; RARE EARTH COMPLEXES; SPECTRA; SYNTHESIS

Optional Information

Notes
10 refs., 2 figs., 3 tabs.