Published April 1981 | Version v1
Journal article

Calculation of the appearance-potential spectrum of YVO4 in the cluster approximation

  • 1. AN SSSR, Sverdlovsk. Inst. Fiziki Metallov
  • 2. AN SSSR, Sverdlovsk. Inst. Khimii

Description

Interpretation of the V L3 AP (appearance potential) spectrum of YVO4 is carried out on the basis of electronic structure calculations for the [VO4]3- cluster using the Xα-scattered-wave SCF method. The transiton-state method has been used for the calculation of two-electron transiton energies, forming the appearance-potential spectrum. It is shown that correct description of the AP spectrum can be obtained in the one-electron approximation. (orig.)

Additional details

Publishing Information

Journal Title
J. Electron Spectrosc. Relat. Phenom.
Journal Volume
22
Journal Issue
3/4
Series
J. Electron Spectrosc. Relat. Phenom.
Journal Page Range
277-281
ISSN
0368-2048

INIS

Country of Publication
Netherlands
Country of Input or Organization
Netherlands
INIS RN
13648795
Subject category
S74: ATOMIC AND MOLECULAR PHYSICS;
Resource subtype / Literary indicator
Numerical Data
Descriptors DEI
ELECTRONIC STRUCTURE; ENERGY LEVELS; ENERGY-LEVEL TRANSITIONS; MOLECULAR ORBITAL METHOD; THEORETICAL DATA; VANADATES; YTTRIUM COMPOUNDS
Descriptors DEC
DATA; INFORMATION; NUMERICAL DATA; OXYGEN COMPOUNDS; TRANSITION ELEMENT COMPOUNDS; VANADIUM COMPOUNDS