Published April 15, 1986 | Version v1
Journal article

Vibrations of regular boron icosahedra

  • 1. Department of Physics and Astronomy, The University of New Mexico, Albuquerque, New Mexico 87131

Description

The B12 icosahedron is a part of elemental boron crystals and a number of boron molecules. Group properties of a regular icosahedron are well-known, but the normal modes have not been pictured heretofore. There are eight distinct frequencies for the thirty modes with 1-fold, 3-fold, 4-fold, and 5-fold degeneracies. Oscillations are here pictured in terms of three equilibrium desciptions: one involves two parallel regular pentagons and two polar atoms, a second has two polar triangles and an equatorial puckered hexagon, while the third consists of six pairs of atoms on opposite faces of a cube. The visualizations should prove useful in application to spectra interpretation, substituent atom location, polaron formation and hopping, and possibly heat conduction in boron-rich borides

Additional details

Publishing Information

Journal Title
AIP Conf. Proc.
Journal Volume
140
Journal Issue
1
Series
AIP Conf. Proc.
Journal Page Range
305-311
ISSN
0094-243X
CODEN
APCPC

Conference

Title
International conference on the physics and chemistry of boron and boron-rich borides.
Dates
29-31 Jul 1985.
Place
Albuquerque, NM (USA).

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
17071942
Subject category
S36: MATERIALS SCIENCE;
Resource subtype / Literary indicator
Conference
Descriptors DEI
BORON; CRYSTALS; GROUP THEORY; LATTICE VIBRATIONS; MOLECULES; NORMAL-MODE ANALYSIS; POLARONS; THERMAL CONDUCTIVITY
Descriptors DEC
ELEMENTS; MATHEMATICS; PHYSICAL PROPERTIES; QUASI PARTICLES; SEMIMETALS; THERMODYNAMIC PROPERTIES

Optional Information

Secondary number(s)
CONF-850786--.