Published July 1975
| Version v1
Journal article
Radiation and chemical oxidation of Ce3+ and reduction of Ce4+ in LiCl solutions during α- and γ-radiolysis
Creators
Description
Radiation-chemical oxidation of Ce3+ and reduction of Ce4+ in lithium chloride ((LiCl) = 3-10 M, (HCl) = 0,1-0,2 M) solutions were investigated. It was established that oxidation of Ce3+ being determined by α-radiolysis, reduction - by γ-radiolysis. Output of oxidizing agent - Cl2 - radical during α-radiolysis was higher than the sum of reductant output in euivalents (H2O2,H), and during γ-radiolysis - lower. Rate constant K(Ce3++Cl2-)=(0,8-4,0)x104 l/mol sec
Additional details
Additional titles
- Original title (Russian)
- Радиационнохимическое окисление Cе
Publishing Information
- Journal Title
- Khim. Vys. Ehnerg.
- Journal Volume
- 9
- Journal Issue
- 4
- Series
- Khim. Vys. Ehnerg.
- Journal Page Range
- 357-360
INIS
- Country of Publication
- USSR
- Country of Input or Organization
- USSR
- INIS RN
- 7278021
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- AQUEOUS SOLUTIONS; CERIUM COMPOUNDS; CHEMICAL REACTION KINETICS; LITHIUM CHLORIDES; OXIDATION; QUANTITY RATIO; RADIOLYSIS; REDUCTION
- Descriptors DEC
- ALKALI METAL COMPOUNDS; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; CHLORIDES; CHLORINE COMPOUNDS; DECOMPOSITION; DISPERSIONS; HALIDES; HALOGEN COMPOUNDS; HOMOGENEOUS MIXTURES; KINETICS; LITHIUM COMPOUNDS; MIXTURES; RADIATION EFFECTS; RARE EARTH COMPOUNDS; REACTION KINETICS; SOLUTIONS
Optional Information
- Notes
- For English translation see the journal High Energy Chem.