Published September 1, 2003 | Version v1
Journal article

On the two principal curvatures as potential barriers in a model of complex matter agglomeration

Description

We show that matter agglomeration mesoscopic phenomena of irreversible type are well described by nonequilibrium thermodynamics formalism. The description assumes that the thermodynamic (internal) state variables are in local equilibrium, and uses the well-known flux-force relations, with the Onsager coefficients involved, ending eventually up at a local conservation law of the Fokker-Planck type. Within the framework of the formalism offered the first two curvatures, characterizing the structure of the agglomerates, are associated with a suitable choice of a physical potential governing the system. It turns out that a certain choice of the potential of power-law type leads to emphasizing the role of the Gaussian curvature while another choice in logarithmic form results in a pronounced role of the mean curvature. The offered modeling has been related successfully with a statistical-mechanical polycrystalline matter evolution introduced for physical-metallurgical purposes, and modified for a use in biophysical soft-matter agglomerations

Additional details

Identifiers

DOI
10.1016/S0301-0104(03)00295-7;
arXiv
arXiv:cond-mat/9903027v1;
PII
S0301010403002957;

Publishing Information

Journal Title
Chemical Physics
Journal Volume
293
Journal Issue
2
Journal Page Range
p. 169-177
ISSN
0301-0104
CODEN
CMPHC2

INIS

Country of Publication
Netherlands
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
38084428
Subject category
S74: ATOMIC AND MOLECULAR PHYSICS;
Descriptors DEI
AGGLOMERATION; EQUILIBRIUM; FOKKER-PLANCK EQUATION; POLYCRYSTALS; POTENTIALS; SIMULATION; THERMODYNAMICS
Descriptors DEC
CRYSTALS; DIFFERENTIAL EQUATIONS; EQUATIONS; PARTIAL DIFFERENTIAL EQUATIONS

Optional Information

Copyright
Copyright (c) 2003 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.