Published February 1982 | Version v1
Journal article

Extraction-spectrophotometric determination of ruthenium (3), rhodium (3) and iridium (3) by reaction with α-benzylmonooxime in the presence of carbonate ion

  • 1. Moskovskij Gosudarstvennyj Univ. (USSR)

Description

An extraction-spectrophotometric method of ruthenium(3) determination in mixture with α-benzylmonooxime(BO) in the presence of carbonate ion is developed. Ru with BO forms the complex of 1:2 composition of pink-violet colour (lambdasub(max)=480 nm) in the presence of carbonate ion and at pH 8.5-9.5. The complex is non-soluble in the water and is extracted with chloroform (R approximately 100%). The optimal range of the Ru determined concentration equals to 0.5-7.6 mkg/ml

Additional details

Additional titles

Original title (Russian)
Экстракционно-спектрофотометрическое определение рутения(III), родия(III) и иридия(III) по реакции с α-бензилмонооксимом в присутствии карбонат-иона

Publishing Information

Journal Title
Zh. Anal. Khim.
Journal Volume
37
Journal Issue
2
Series
Zh. Anal. Khim.
Journal Page Range
285-288
ISSN
0044-4502

Optional Information

Notes
For English translation see the journal Journal of Analytical Chemistry of the USSR (USA).