Published 1978
| Version v1
Journal article
Collision induced dissociation of Cs2 studied by atom-molecule-exchange optical pumping
Description
Using the atom-molecule-exchange optical pumping method the collision induced dissociation of Cs2 in the foreign gas atmospheres He, Ne, Ar, Kr, N2 and CH4 is studied. The rate constant for dissociation is found to have an Arrhenius form and good agreement of the activation energy with the spectoscopically determined bond dissociation energy is obtained. (orig.)
Abstract (German)
Unter Verwendung der optischen Pumpmethode mit Atom-Molekuel-Austausch wurde die Stossinduzierte Dissoziation von CS2 in den Fremdgasatmosphaeren He, Ne, Ar, Kr, N2 und CH4 untersucht. Fuer die Dissoziationskonstante ergibt sich ein Arrheniusgesetz, und man erhaelt gute Uebereinstimmung zwischen Aktivierungsenergie und der spektroskopisch bestimmten Dissoziationsenergie. (orig.)Additional details
Identifiers
- DOI
- 10.1007/bf01406794;
Publishing Information
- Journal Title
- Zeitschrift f�r Physik A Atoms and Nuclei
- Journal Volume
- 284
- Journal Issue
- 3
- Series
- Z. Phys., A.
- Journal Page Range
- 253-260
- ISSN
- 0340-2193
INIS
- Country of Publication
- Germany
- Country of Input or Organization
- Germany
- INIS RN
- 9380387
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS;
- Descriptors DEI
- ARGON; ATOM-MOLECULE COLLISIONS; CESIUM; DISSOCIATION; DISSOCIATION ENERGY; HELIUM; INTEGRAL CROSS SECTIONS; KRYPTON; METHANE; NEON; NITROGEN; OPTICAL PUMPING; RELAXATION; TEMPERATURE DEPENDENCE
- Descriptors DEC
- ALKALI METALS; ALKANES; ATOM COLLISIONS; COLLISIONS; CROSS SECTIONS; ELEMENTS; ENERGY; HYDROCARBONS; METALS; MOLECULE COLLISIONS; NONMETALS; ORGANIC COMPOUNDS; RARE GASES
Optional Information
- Notes
- 6 figs.; 2 tabs.; 28 refs.; Updated automatically by Metadata and Full-Text Enrichment Agent