Published November 3, 1997
| Version v1
Journal article
[Ru20H4(Cu)6(Cl)2(CO)48]4-: A new high nuclearity copper-ruthenium cluster
- 1. Cambridge Univ. (United Kingdom). Dept. of Chemistry
Description
A precursor for Cu/Ru mixed-metal catalysts? This is one of the potential applications of the title cluster, which can be isolated as the nBu4N+ salt from the reaction of [(Ph3P)2N]2[Ru10H2(CO)25] with nBu4NOH/H2O, [Cu(MeCN)4], and (Ph3P)2NCl. (orig.)
Additional details
Publishing Information
- Journal Title
- Angewandte Chemie. International Edition in English
- Journal Volume
- 36
- Journal Issue
- 20
- Journal Page Range
- p. 2227-2228.
- ISSN
- 0570-0833
- CODEN
- ACIEAY
INIS
- Country of Publication
- Germany
- Country of Input or Organization
- Germany
- INIS RN
- 29007119
- Subject category
- S36: MATERIALS SCIENCE; S36: MATERIALS SCIENCE;
- Descriptors DEI
- BOND LENGTHS; CARBONYLS; CHEMICAL PREPARATION; COPPER CHLORIDES; CRYSTAL STRUCTURE; RUTHENIUM COMPOUNDS
- Descriptors DEC
- CHLORIDES; CHLORINE COMPOUNDS; COPPER COMPOUNDS; COPPER HALIDES; HALIDES; HALOGEN COMPOUNDS; SYNTHESIS; TRANSITION ELEMENT COMPOUNDS