Published April 15, 2024 | Version v1
Journal article

Screened hydrogen model of excitons in semiconducting nanoribbons

  • 1. Departamento de Ciencias, Universidad Privada del Norte, Lima 15434, Peru
  • 2. Instituto de Física Teórica, Universidade Estadual Paulista (UNESP), Rua Dr. Bento T. Ferraz, 271, São Paulo, SP 01140-070, Brazil

Description

The optical response of quasi-one-dimensional systems is often dominated by tightly bound excitons that significantly influence their basic electronic properties. Despite their importance for device performance, accurately predicting their excitonic effects typically requires computationally demanding many-body approaches. Here, we present a simplified model to describe the static macroscopic dielectric function, which depends only on the width of the quasi-one-dimensional system and its polarizability per unit length. We show that at certain interaction distances, the screened Coulomb potential is greater than its bare counterpart, which results from the enhanced repulsive electron-electron interactions. As a test case, we study 14 different nanoribbons, 12 of them armchair graphene nanoribbons of different families. Initially, we devised a simplified equation to estimate the exciton binding energy and extension that provides results comparable to those from the full Bethe-Salpeter equation, albeit for a specific nanoribbon family. Then, we used our proposed screening potential to solve the 1D Wannier-Mott equation, which turns out to be a broad approach that is able to predict binding energies that match quite well the ones obtained with the Bethe-Salpeter equation, irrespective of the nanoribbon family.

Additional details

Identifiers

DOI
10.1103/PhysRevB.109.165425;
Crossref Funder ID
10.13039/501100001807; 10.13039/501100003593;

Publishing Information

Journal Title
Physical Review B
Journal Volume
109
Journal Issue
16
Journal Page Range
8 pgs.
ISSN
1550-235X

Optional Information

Copyright
©2024 American Physical Society
Contract/Grant/Project number
2016/01343-7; 2017/02317-2; 2021/14335-0; 408038/2022-5; 307710/2019-0
Notes
Record automatically processed
Funding organization
Fundação de Amparo à Pesquisa do Estado de São Paulo; Conselho Nacional de Desenvolvimento Científico e Tecnológico