Published 1981 | Version v1
Journal article

Structural studies on the actinide carboxylates

  • 1. Consiglio Nazionale delle Ricerche, Padua (Italy). Lab. di Chimica e Tecnologia dei Radioelementi
  • 2. Consejo Superior de Investigaciones Cientificas, Madrid (Spain). Inst. de Quimica Inorganica

Description

The title compound crystallizes in the triclinic system. The space group and lattice parameters are reported. The structure is built up from two distinct coordination polyhedra, one is formed by the uranium which is at a centre of a pentagonal bipyramid, the other by the potassium cations heptacoordinate to oxygen atoms either belonging to the maleic ligands or to the uranyl group. The uranium polyhedra are connected through bridging maleato groups. The maleato-U-maleato chains in the direction of the c axis are held together through the potassium coordination polyhedra. (author)

Additional details

Additional titles

Subtitle (English)
7. The crystal and molecular structure of potassium maleate hydrogenmaleate dioxouranate (VI); [UO_2(C_4H_2O_4)K(C_4H_3O_4)]

Publishing Information

Journal Title
J. Inorg. Nucl. Chem.
Journal Volume
43
Journal Issue
12
Series
J. Inorg. Nucl. Chem.
Journal Page Range
3203-3207
ISSN
0022-1902