Published 1981
| Version v1
Journal article
Structural studies on the actinide carboxylates
- 1. Consiglio Nazionale delle Ricerche, Padua (Italy). Lab. di Chimica e Tecnologia dei Radioelementi
- 2. Consejo Superior de Investigaciones Cientificas, Madrid (Spain). Inst. de Quimica Inorganica
Description
The title compound crystallizes in the triclinic system. The space group and lattice parameters are reported. The structure is built up from two distinct coordination polyhedra, one is formed by the uranium which is at a centre of a pentagonal bipyramid, the other by the potassium cations heptacoordinate to oxygen atoms either belonging to the maleic ligands or to the uranyl group. The uranium polyhedra are connected through bridging maleato groups. The maleato-U-maleato chains in the direction of the c axis are held together through the potassium coordination polyhedra. (author)
Additional details
Additional titles
- Subtitle (English)
- 7. The crystal and molecular structure of potassium maleate hydrogenmaleate dioxouranate (VI); [UO_2(C_4H_2O_4)K(C_4H_3O_4)]
Publishing Information
- Journal Title
- J. Inorg. Nucl. Chem.
- Journal Volume
- 43
- Journal Issue
- 12
- Series
- J. Inorg. Nucl. Chem.
- Journal Page Range
- 3203-3207
- ISSN
- 0022-1902
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- United Kingdom
- INIS RN
- 13693466
- Subject category
- S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Resource subtype / Literary indicator
- Numerical Data
- Descriptors DEI
- BOND ANGLE; BOND LENGTHS; COORDINATION VALENCES; CRYSTAL STRUCTURE; EXPERIMENTAL DATA; LATTICE PARAMETERS; LIGANDS; MALEIC ACID; MOLECULAR STRUCTURE; POTASSIUM COMPOUNDS; SPACE GROUPS; URANYL COMPLEXES; X-RAY DIFFRACTION
- Descriptors DEC
- ACTINIDE COMPLEXES; ALKALI METAL COMPOUNDS; CARBOXYLIC ACIDS; COHERENT SCATTERING; COMPLEXES; DATA; DICARBOXYLIC ACIDS; DIFFRACTION; INFORMATION; NUMERICAL DATA; ORGANIC ACIDS; ORGANIC COMPOUNDS; SCATTERING; SYMMETRY GROUPS; URANIUM COMPLEXES; VALENCE