Published 1993 | Version v1
Book

Ab initio calculations of some rotational kinetic isotope effects

  • 1. Univ. of California, Los Angeles, CA (United States)

Description

The deuterium kinetic isotope effect for cis/trans isomerization of several molecules has been studied using ab initio calculations. The magnitude of the rotational kinetic isotope effect is discussed, in the context of its origins, its temperature dependence, and substituent effects

Additional details

Publishing Information

Publisher
American Chemical Society.
Imprint Place
Washington, DC (United States)
Imprint Title
205th ACS national meeting
Imprint Pagination
1951 p.
Journal Page Range
p. 57, Paper ORGN 46.

Conference

Title
205. American Chemical Society national meeting.
Dates
28 Mar - 2 Apr 1993.
Place
Denver, CO (United States).

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
26004809
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Resource subtype / Literary indicator
Conference
Descriptors DEI
CHEMICAL REACTION KINETICS; DEUTERIUM; ISOMERIZATION; ISOTOPE EFFECTS; MOLECULES; ROTATION; STEREOCHEMISTRY; TEMPERATURE DEPENDENCE
Descriptors DEC
CHEMICAL REACTIONS; HYDROGEN ISOTOPES; ISOTOPES; KINETICS; LIGHT NUCLEI; NUCLEI; ODD-ODD NUCLEI; REACTION KINETICS; STABLE ISOTOPES

Optional Information

Secondary number(s)
CONF-930304--.