Published October 15, 1987
| Version v1
Journal article
Tetrachlorophosphonium(V) tetrachloroaurate(III)
- 1. Goettingen Univ. (Germany, F.R.). Inst. fuer Anorganische Chemie
Description
[PCl4][AuCl4], Mr=511.6, orthorhombic, Imma, a=15.734(5), b=12.433(4), c=11.646(3) A, V=2278 A3, Z=8, Dx=2.98 Mg m-3, λ(MoKα)=0.71069 A, μ(MoKα)=14.9 mm-1, F(000)=1840, T=293 K, R=0.045, wR=0.047 for 1325 unique observed reflections [F>4σ(F)]. The structure consists of isolated PCl4+ and AuCl4- ions with crystallographic symmetry 2 and mm2 respectively; there are two independent anions. The cations and anions form independent layers near x=0.25, 0.75 and 0,0.5, respectively. [PCl4][AuCl4] is isostructural with [PCl4][ICl4]. The independent bond lenghts are P-Cl 1.924(2), 1.930(2), Au-Cl 2.274(3), 2.273(3), 2.270(3), 2.277(5) and 2.293(4) A. (orig.)
Additional details
Publishing Information
- Journal Title
- Acta Crystallogr., Sect. C
- Journal Volume
- 43
- Journal Issue
- 10
- Series
- Acta Crystallogr., Sect. C.
- Journal Page Range
- 1857-1859
- ISSN
- 0108-2701
- CODEN
- ACSCE
INIS
- Country of Publication
- Denmark
- Country of Input or Organization
- Denmark
- INIS RN
- 19029635
- Subject category
- S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
- Resource subtype / Literary indicator
- Numerical Data
- Descriptors DEI
- BOND ANGLE; BOND LENGTHS; CRYSTAL STRUCTURE; EXPERIMENTAL DATA; GOLD CHLORIDES; LATTICE PARAMETERS; MEDIUM TEMPERATURE; ORTHORHOMBIC LATTICES; PHOSPHORUS CHLORIDES; X-RAY DIFFRACTION
- Descriptors DEC
- CHLORIDES; CHLORINE COMPOUNDS; COHERENT SCATTERING; CRYSTAL LATTICES; DATA; DIFFRACTION; GOLD COMPOUNDS; HALIDES; HALOGEN COMPOUNDS; INFORMATION; NUMERICAL DATA; PHOSPHORUS COMPOUNDS; SCATTERING; TRANSITION ELEMENT COMPOUNDS