Published November 1989
| Version v1
Journal article
Complexes of technetium, rhenium, and rhodium with sexidentate Schiff-base ligands
Description
The monocationic technetium (IV) and rhenium (IV) complexes with the sexidentate Schiff-base ligands tris[2-(2'-hydroxybenzylideneethyl)]amine and its substituted derivatives have been prepared and their electrochemical properties studied. The variable-temperature 90.6 MHz 13C-{1H} n.m.r. spectrum of the rhodium (III) complex of tris[2-(2-hydroxy-5'-isopropylbenzylideneethyl)-amine] has been observed, indicating fluxionality at temperatures above 218 K. (author)
Additional details
Publishing Information
- Journal Title
- Journal of the Chemical Society (London), Dalton Transactions
- Journal Issue
- no.11
- Series
- J. Chem. Soc., Dalton Trans.
- ISSN
- 0300-9246
- CODEN
- JCDTB
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- United Kingdom
- INIS RN
- 21030677
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- CHEMICAL PREPARATION; INFRARED SPECTRA; LIGANDS; NMR SPECTRA; RADIOPHARMACEUTICALS; RHENIUM COMPLEXES; RHODIUM COMPLEXES; SCHIFF BASES; STRUCTURAL CHEMICAL ANALYSIS; TECHNETIUM COMPLEXES; TECHNETIUM 99; VOLTAMETRY
- Descriptors DEC
- BETA DECAY RADIOISOTOPES; BETA-MINUS DECAY RADIOISOTOPES; COMPLEXES; DRUGS; HOURS LIVING RADIOISOTOPES; IMINES; INTERMEDIATE MASS NUCLEI; INTERNAL CONVERSION RADIOISOTO; ISOMERIC TRANSITION ISOTOPES; ISOTOPES; LABELLED COMPOUNDS; MATERIALS; NUCLEI; ODD-EVEN NUCLEI; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; RADIOACTIVE MATERIALS; RADIOISOTOPES; SPECTRA; SYNTHESIS; TECHNETIUM ISOTOPES; TRANSITION ELEMENT COMPLEXES; YEARS LIVING RADIOISOTOPES