Published June 1982 | Version v1
Journal article Metadata-only

Coordination compounds of tetrachlorides of titanium, zirconium and hafnium with semicarbazides

Creators

  • 1. Kishinevskij Gosudarstvennyj Univ. (USSR)
  • 2. AN SSSR, Moscow. Inst. Obshchej i Neorganicheskoj Khimii
  • 3. Kishinevskij Politekhnicheskij Inst. (USSR)

Description

Adducts of titanium, zirconium and hafnium tetrachlorides with semicarbazide of the composition 1:1 have been synthesized. Bidentate coordination of semicarbazide is suggested on the basis of infrared spectra. Formation heats of adducts are determined by the thermochemical method. It is shown that hafnium forms stronger compounds than zirconium

Additional details

Additional titles

Original title (Russian)
Координационные соединения тетрахлоридов титана, циркония и гафния с семикарбазидом

Publishing Information

Journal Title
Zh. Neorg. Khim.
Journal Volume
27
Journal Issue
6
Series
Zh. Neorg. Khim.
Journal Page Range
1432-1435
ISSN
0044-457X

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
14740920
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ADDUCTS; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; FORMATION HEAT; HAFNIUM CHLORIDES; INFRARED SPECTRA; SEMICARBAZIDES; ZIRCONIUM CHLORIDES
Descriptors DEC
CARBONIC ACID DERIVATIVES; CHLORIDES; CHLORINE COMPOUNDS; ENTHALPY; HAFNIUM COMPOUNDS; HALIDES; HALOGEN COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; REACTION HEAT; SPECTRA; SYNTHESIS; THERMODYNAMIC PROPERTIES; TRANSITION ELEMENT COMPOUNDS; ZIRCONIUM COMPOUNDS

Optional Information

Notes
For English translation see the journal Russian Journal of Inorganic Chemistry (UK).