Published July 2006
| Version v1
Journal article
Synthesis, crystal structure and magnetic properties of an alternating manganese chain
- 1. CEMDRX, Departamento de Fisica, Faculdade de Ciencias e Tecnologia, Universidade de Coimbra, P-3004-516 COIMBRA (Portugal)
- 2. ETSIA, Universidad de Vallodolid, Avda Madrid 57, 34004 Palencia (Spain)
Description
A new 1D complex has been prepared and characterized. X-ray single crystal structure confirms that the Mn(II) ions assemble in alternating chains with Mn-Mn distances of 3.8432(13) and 4.4428(14) A. A 3D network of hydrogen bonds links the chains together. The temperature dependence of the magnetic susceptibility reveals that this compound undergoes a magnetic transition and exhibits an antiferromagnetic interaction in the low-temperature phase with two alternating exchange interactions of -2.32(1) and -5.55(1) cm-1. - Graphical abstract: Portion of the dimeric manganese chain showing the two alternating exchange interactions paths
Additional details
Identifiers
- DOI
- 10.1016/j.jssc.2006.03.024;
- PII
- S0022-4596(06)00172-1;
Publishing Information
- Journal Title
- Journal of Solid State Chemistry
- Journal Volume
- 179
- Journal Issue
- 7
- Journal Page Range
- p. 2054-2058
- ISSN
- 0022-4596
- CODEN
- JSSCBI
INIS
- Country of Publication
- United States
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 38067800
- Subject category
- S36: MATERIALS SCIENCE;
- Descriptors DEI
- ANTIFERROMAGNETISM; CRYSTAL STRUCTURE; EXCHANGE INTERACTIONS; MAGNETIC SUSCEPTIBILITY; MANGANESE COMPLEXES; MONOCRYSTALS; SYNTHESIS; TEMPERATURE DEPENDENCE; X RADIATION
- Descriptors DEC
- COMPLEXES; CRYSTALS; ELECTROMAGNETIC RADIATION; INTERACTIONS; IONIZING RADIATIONS; MAGNETIC PROPERTIES; MAGNETISM; PHYSICAL PROPERTIES; RADIATIONS; TRANSITION ELEMENT COMPLEXES
Optional Information
- Copyright
- Copyright (c) 2006 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.