Published October 1992 | Version v1
Journal article Metadata-only

Photoelectron spectroscopy of f-element organometallic complexes. 8. DV-Xα and gas-phase UV photoelectron spectroscopic investigation of the electronic structure of tris (η5-cyclopentadienyl)uranium(IV) complexes

Creators

  • 1. Universita di Catania, Catania (Italy)

Description

The electronic structures of a series of closely related U(η5-C5H5)3L (L = -CH3, -NH2, -BH4, - NCS) complexes has been studied using the SCF Hartree-Fock-Slater first-principles discrete variational Xα method in combination with HeI and HeII UV photoelectron spectroscopy. The theoretical results reproduce the experimental HeI and He II photoelectron spectroscopic data, thus providing a reliable description of the metal-ligand bonding. 29 refs., 9 figs., 6 tabs

Additional details

Publishing Information

Journal Title
Organometallics
Journal Volume
11
Journal Issue
10
Journal Page Range
p. 3248-3257.
ISSN
0276-7333
CODEN
ORGND7

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
27067762
Subject category
S36: MATERIALS SCIENCE; S74: ATOMIC AND MOLECULAR PHYSICS;
Descriptors DEI
ELECTRONIC STRUCTURE; ORGANOMETALLIC COMPOUNDS; PHOTOELECTRON SPECTROSCOPY; SELF-CONSISTENT FIELD; URANIUM COMPLEXES
Descriptors DEC
ACTINIDE COMPLEXES; COMPLEXES; ELECTRON SPECTROSCOPY; ORGANIC COMPOUNDS; SPECTROSCOPY