Published March 2019 | Version v1
Journal article

Elemental distribution analysis of copper-based preservative-treated woods by micro XRF method

  • 1. Osaka City University, Graduate School of Engineering, Osaka (Japan)
  • 2. Kyoto University, Graduate School of Agriculture, Kyoto (Japan)

Description

Wood is useful as construction material; however, wood is not strong for decay and insect damages. Generally, injecting copper-based preservative treatment is effective for these damages. However, in some cases, the amount of injection treatment is not enough and homogenous in wood. In previous studies, wood samples had been cut to confirm Cu distribution in the samples. Analytical method for investigating the injection amount of Cu is required in non-destructively and non-contact way. In this study, we attempted to acquire elemental distribution in wood by using micro XRF method. European red pine (Pinus sylvestris) wood was measured by micro XRF instrument manufactured in the laboratory. XRF images of Cu, Ca, and K were measured on the surface and cross section of the wood sample. It was found that the injection depth of copper depended on the structure of wood. In addition, the detection efficiency of Cu fluorescent X-rays was evaluated according to Lambert-Beer's law and compared with the experimental result. (author)

Abstract (Japanese)

木材は昔から構造材料として使用されてきたが,腐朽や虫害に弱いという欠点がある.一般に銅系の防腐剤を木材に注入し腐朽や虫害に対処しているが,注入量不足,注入された防腐剤の不均一性などの問題点がある.今までの研究では,木材中の銅を確認するために切断する必要があった.木材を切断せず全サンプル検査するために,非破壊・非接触的に木材に注入された防腐剤の注入量を評価する方法が求められている.そこで,本研究では微小部蛍光X線分析法を用いて,元素の分布の取得を試みた.試料として防腐処理を施 したオウシュウアカマツ材を用い,当研究室で作製した微小部蛍光X線分析装置を用いて測定した.試料表面と断面のCuとCa, KのXRF イメージング画像を取得した.木材の組織構造に応じて,銅の浸透深さが異なることが分かった.また,銅の蛍光X線の検出可能深さをランペルトーベールの法則から計算した理論値と,実際に実験を行い得られた結果との比較を行った.(著者)

Additional details

Additional titles

Original title (Japanese)
微小部蛍光X線分析法による銅系防腐処理木材の元素分布解析

Publishing Information

Journal Title
X-sen Bunseki No Shinpo
Journal Volume
50
Series
雑誌名:X線分析の進歩
Journal Page Range
p. 105-112
ISSN
0911-7806

Optional Information

Notes
6 refs., 9 figs.