Published March 1988
| Version v1
Journal article
Hydrophobic interactions: Ionic mobilities of tetraphenylphosphonium chloride in aqueous solutions at 25 degree C
Description
The present study provides systematic data of conductivity, transference number and apparent molal volume for Ph4PCl in water at 25 degree C over a concentration range 0.005-0.5 mol-l-1. Transference numbers have been measured by labelling the migrating species with radiotracers 14C for Ph4P+ and 36Cl for the anion. An unexpected concentration dependence for the transference numbers is observed that deviates markedly from that of a simple 1:1 electrolyte. Excess transport properties have been interpreted in terms of cation dimerization induced by hydrophobic interactions
Additional details
Publishing Information
- Journal Title
- Journal of Solution Chemistry
- Journal Volume
- 17
- Journal Issue
- 3
- Series
- J. Solution Chem.
- Journal Page Range
- 203-212
- ISSN
- 0095-9782
- CODEN
- JSLCA
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 21013368
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- AQUEOUS SOLUTIONS; CARBON 14 COMPOUNDS; CHLORINE 36; DIMERIZATION; IONIC CONDUCTIVITY; LABELLING; ORGANIC CHLORINE COMPOUNDS; ORGANIC PHOSPHORUS COMPOUNDS; TRACER TECHNIQUES
- Descriptors DEC
- BETA DECAY RADIOISOTOPES; BETA-MINUS DECAY RADIOISOTOPES; BETA-PLUS DECAY RADIOISOTOPES; CARBON COMPOUNDS; CHEMICAL REACTIONS; CHLORINE ISOTOPES; DISPERSIONS; ELECTRIC CONDUCTIVITY; ELECTRICAL PROPERTIES; ELECTRON CAPTURE RADIOISOTOPES; HOMOGENEOUS MIXTURES; ISOTOPE APPLICATIONS; ISOTOPES; LIGHT NUCLEI; MIXTURES; NUCLEI; ODD-ODD NUCLEI; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; PHYSICAL PROPERTIES; POLYMERIZATION; RADIOISOTOPES; SOLUTIONS; YEARS LIVING RADIOISOTOPES