Published August 1977
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The influence of the medium on the hydrolysis and polymerization of actinides
- 1. Institut za Nuklearne Nauke Boris Kidric, Belgrade (Yugoslavia)
Description
The hydrolysis of thorium(IV) ions in ionic medium (aqueous solutions containing chlorides or nitrates) is studied. A linear free energy relationship (formula given) between changes in the ionic medium (e.g. in chloride concentration) and the hydrolysis reaction is established. To check the applicability of the formula, experiments with thorium(IV) ions in chloride solution media were carried out using potentiometric and calorimetric methods. The experimental results were in agreement with the linear free energy relationship
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Additional details
Additional titles
- Subtitle (English)
- Final report for the period 15 October 1974 - 31 January 1977
Publishing Information
- Imprint Pagination
- 6 p.
- Report number
- IAEA-R--1522-F
INIS
- Country of Publication
- International Atomic Energy Agency (IAEA)
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 9375517
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- AQUEOUS SOLUTIONS; CALORIMETRY; CHLORIDES; FREE ENERGY; HYDROLYSIS; HYDROXIDES; NITRATES; POTENTIOMETRY; THERMODYNAMICS; THORIUM COMPOUNDS
- Descriptors DEC
- ACTINIDE COMPOUNDS; CHEMICAL REACTIONS; CHLORINE COMPOUNDS; DECOMPOSITION; DISPERSIONS; ENERGY; HALIDES; HALOGEN COMPOUNDS; HOMOGENEOUS MIXTURES; HYDROGEN COMPOUNDS; MIXTURES; NITROGEN COMPOUNDS; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; SOLUTIONS; SOLVOLYSIS; THERMODYNAMIC PROPERTIES; TITRATION
Optional Information
- Notes
- thorium.