Published 1986 | Version v1
Book

The chemical potential for interacting fermions in a harmonic potential

  • 1. Univ. of Washington, Seattle, WA

Description

One of the key concepts in density functional theory is the chemical potential. For a fixed Hamiltonian in second-quantized form one may define a sequence of ground state energies E(N) for varying integral number, N, of electrons. The authors define an equation whereby the energy may be logically regarded as piece-wise linear in N with discontinuities in the slope precisely at the points where mu is sought. Topics discussed include N-body harmonic oscillator, as discussion of the results, and speculation on the chemical potential defined as the derivative of E with respect to natural orbital occupation

Additional details

Publishing Information

Publisher
Plenum Press.
Imprint Place
New York, NY (USA)
Imprint Title
Local density approximations in quantum density and solid state physics
Journal Page Range
p. 43-52.

Conference

Title
Local density approximations in quantum chemistry and solid state theory conference.
Dates
10-12 Jun 1982.
Place
Copenhagen (Denmark).