Published 1986
| Version v1
Book
The chemical potential for interacting fermions in a harmonic potential
Description
One of the key concepts in density functional theory is the chemical potential. For a fixed Hamiltonian in second-quantized form one may define a sequence of ground state energies E(N) for varying integral number, N, of electrons. The authors define an equation whereby the energy may be logically regarded as piece-wise linear in N with discontinuities in the slope precisely at the points where mu is sought. Topics discussed include N-body harmonic oscillator, as discussion of the results, and speculation on the chemical potential defined as the derivative of E with respect to natural orbital occupation
Additional details
Publishing Information
- Publisher
- Plenum Press.
- Imprint Place
- New York, NY (USA)
- Imprint Title
- Local density approximations in quantum density and solid state physics
- Journal Page Range
- p. 43-52.
Conference
- Title
- Local density approximations in quantum chemistry and solid state theory conference.
- Dates
- 10-12 Jun 1982.
- Place
- Copenhagen (Denmark).
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 18062739
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS; S71: CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS;
- Resource subtype / Literary indicator
- Conference
- Descriptors DEI
- ATOMIC MODELS; ATOMS; BOUNDARY CONDITIONS; COULOMB FIELD; ELECTRONEGATIVITY; ELECTRONIC STRUCTURE; ELECTRONS; ENERGY LEVELS; FERMIONS; HAMILTONIANS; HARMONIC OSCILLATOR MODELS; INTERACTION RANGE; PHYSICAL CHEMISTRY; POTENTIALS; QUANTIZATION; QUANTUM MECHANICS; SPIN; WAVE FUNCTIONS
- Descriptors DEC
- ANGULAR MOMENTUM; CHEMISTRY; DISTANCE; ELECTRIC FIELDS; ELEMENTARY PARTICLES; FUNCTIONS; LEPTONS; MATHEMATICAL MODELS; MATHEMATICAL OPERATORS; MECHANICS; PARTICLE PROPERTIES; QUANTUM OPERATORS