Published February 20, 2012
| Version v1
Journal article
Curium(III) borate shows coordination environments of both plutonium(III) and americium(III) borates
Creators
- 1. Department of Chemistry and Biochemistry and Department of Civil Engineering and Geological Sciences, University of Notre Dame, IN (United States)
- 2. Forschungszentrum Juelich GmbH, Institute for Energy and Climate Research (IEK-6) (Germany)
- 3. Department of Crystallography, University of Kiel (Germany)
- 4. Chemistry Division, Argonne National Laboratory, Argonne, IL (United States)
- 5. Chemical Sciences Division, Transuranium Research Laboratory, Oak Ridge National Laboratory, Oak Ridge, TN (United States)
Description
The two faces of curium: The first curium borate has been prepared showing a complex structure with coordination environments for CmIII that are found in both PuIII and AmIII borates. Time-resolved laser-induced photoluminescence studies as well as X-ray diffraction experiments show two distinct CmIII sites with different coordination environments. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)
Availability note (English)
Available from: http://dx.doi.org/10.1002/anie.201107956Additional details
Identifiers
Publishing Information
- Journal Title
- Angewandte Chemie (International Edition)
- Journal Volume
- 51
- Journal Issue
- 8
- Journal Page Range
- p. 1869-1872
- ISSN
- 1433-7851
- CODEN
- ACIEF5
INIS
- Country of Publication
- Germany
- Country of Input or Organization
- Germany
- INIS RN
- 48061883
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- AMERICIUM COMPOUNDS; BORATES; CURIUM COMPOUNDS; PHOTOLUMINESCENCE; PLUTONIUM COMPOUNDS; X-RAY DIFFRACTION
- Descriptors DEC
- ACTINIDE COMPOUNDS; BORON COMPOUNDS; COHERENT SCATTERING; DIFFRACTION; EMISSION; LUMINESCENCE; OXYGEN COMPOUNDS; PHOTON EMISSION; SCATTERING; TRANSPLUTONIUM COMPOUNDS; TRANSURANIUM COMPOUNDS
Optional Information
- Notes
- With 5 figs., 32 refs.