Published 1989 | Version v1
Journal article

Association of alkylammonium salts in low-polarity solvents

Description

29 binary alkylammonium salts (AS), used for extraction and separation of rare and radioactive elements, were taken as examples to show that in the region of high dilutions the concentration dependences of solvent activity is reproduced by mA2/lnfS=A''√mA + B''mA equation much better, than by mA2/lnfS=A' + B'mA equation. A', B', A'', B'' parameters for considered systems were found. Expression for calculating coefficients of AS activity, obtained in result of analytical integration of Giibs-Duhem equation, was suggested

Additional details

Additional titles

Subtitle (English)
Communication 1. Determination of activity of alkylammonium salts
Original title (Russian)
Ассоциация солей алкиламмония в малополярных растворителях
Original subtitle (Russian)
Soobshchenie 1. Opredelenie aktivnosti solej alkilammoniya.

Publishing Information

Journal Title
Radiokhimiya
Journal Volume
31
Journal Issue
5
Series
Radiokhimiya.
Journal Page Range
57-60
ISSN
0033-8311
CODEN
RADKA

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
21082150
Subject category
S11: NUCLEAR FUEL CYCLE AND FUEL MATERIALS;
Descriptors DEI
EQUATIONS; ORGANIC SOLVENTS; QUANTITY RATIO; QUATERNARY COMPOUNDS; RADIOISOTOPES; SOLVENT EXTRACTION; THERMODYNAMIC ACTIVITY
Descriptors DEC
AMINES; ISOTOPES; NONAQUEOUS SOLVENTS; ORGANIC COMPOUNDS; SEPARATION PROCESSES; SOLVENTS