TMAP2000 Use

The TMAP Code was written in the late 1980s as a tool for safety analysis of systems involving tritium. Since then it was upgraded to TMAP4 and used in numerous applications including experiments supporting fusion safety predictions for advanced systems such as the International Thermonuclear Experimental Reactor (ITER), and estimates involving tritium production technologies. Its further upgrade to TMAP2000 was accomplished in response to several needs. TMAP and TMAP4 had the capacity to deal with only a single trap for diffusing gaseous species in solid structures. TMAP2000 has been revised to include up to three separate traps and to keep track separately of each of up to 10 diffusing species in each of the traps. A difficulty in the original code dealing with heteronuclear molecule formation such as HD and DT has been removed. Under equilibrium boundary conditions such as Sieverts' law, TMAP2000 generates heteronuclear molecular partial pressures when solubilities and partial pressures of the homonuclear molecular species and the equilibrium stoichiometry are provided. A further sophistication is the addition of non-diffusing surface species and surface binding energy dynamics options. Atoms such as oxygen or nitrogen on metal surfaces are sometimes important in molecule formation with diffusing hydrogen isotopes but do not themselves diffuse appreciably in the material. TMAP2000 will accommodate up to 30 such surface species, allowing the user to specify relationships between those surface concentrations and populations of gaseous species above the surfaces. Additionally, TMAP2000 allows the user to include a surface binding energy and an adsorption barrier energy and includes asymmetrical diffusion between the surface sites and regular diffusion sites in the bulk. All of the previously existing features for heat transfer, flows between enclosures, and chemical reactions within the enclosures have been retained, but the allowed problem size and complexity have been significantly increased to take advantage of the greater memory and speed available on modern computers. This report provides users of TMAP2000 with the specialized information they will need to properly construct the input files used with the code. It assumes the user has and is familiar with the TMAP4 Users Manual, and it focuses on changes from TMAP4 input file requirements